Some Important Question for Topics in Physical Chemistry-I PS01CCHE23

 Note:

These questions are helpful for the preparation of exams, it doesn't mean that you should prepare only this.

Prepare all units completely and then go with this Question Bank.

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Unit 3 Electrochemistry

1.     Explain the thermodynamics of electrified interface using important equations.

2.     Write the Lippman’s equation for surface excess and explain each term.

3.     Discuss the structure of electrified interface with diagram.

4.     Explain the ion solvent interaction in cell.

5.     Derive the Debye-Huckel-Onsager equation.

6.     Explain Bockris-Devanathan theory.

7.     Define exchange current density.

8.     Write a note on exchange current density.

9.     What is Over Potential? Explain various types of Over Potential. or

What is Over Voltage? Explain various types of Over Voltage. or

What is Bubble Over Voltage? Explain various types of Bubble Over Voltage.

10.                        What are the factors affecting on over voltage?

11.                        Write a note on Butler-Volmer equation.

12.                        Explain Tafel plots and Tafel equations.

13.                        What are the application of Electrochemistry?

14.                        Write only Butler-Volmer equation.

15.                        Explain the Helmholtz Electrical Double Layer model.

16.                        Explain the Gouy Chapman Electrical Double Layer model.

17.                        Explain the Stern Electrical Double Layer model.


Unit 4 Surface Tension

1.           Explain surface tension.

2.           Give brief account on surfactants.

3.           Classify various surface active agents (with 3 examples of each).

4.           Derive young Laplace equation.

5.           Write a note on cationic and anionic surfactant (with 3 examples of each).

6.           Explain: critical micelle concentration (CMC).

7.           What are the factors affecting on CMC?

8.           Explain in detail: thermodynamics of micelization.

9.           Explain various CMC curves.

10.      Discuss the Mass Action model and Phase separation model for micelization.

11.      What is a role of surfactants?

12.      Explain capillary action.

13.      Why mercury does not wet the glass, but water wets?

14.      Write the Kelvin equation.

15.      A sample of chloroform rise to a height of 3.67 cm at 20° C in a capillary tube having an inside radius of 0.01 cm. what is the surface tension of chloroform at this temperature? Density of chloroform is 1.476 g/cm3

16.      Find out the radius of capillary in which water is rice up to 3 mm height. Surface tension of water = 0.07259 Kg/S2, density of water = 1000 Kg/m3, gravitational acceleration = 9.8 m/s2

17.      Estimate the height of water insdie the capillary tube at 0.5 mm radius, surface tension is 72 mN/m and density is 995.6 Kg/m3 and contact angle θ = 0°

18.      Calculate the pressure inside a 1μm diameter droplet of water in air at 293 K and 1 atm pressure given that surface tension of water 72.8×10-3 N/m

19.      Find out the radius of capillary in which water is rice up to 3 mm height. Surface tension of water = 0.07259 Kg/S2, density of water = 1000 Kg/m3, gravitational acceleration = 9.8 m/s2

20.      Find out the radius of capillary in which methanol is rice up to 0.30 mm height. Surface tension of water = 0.0227 N/m, density of methanol = 786.2 Kg/m3, gravitational acceleration = 9.8 m/s2 and contact angle is 0°.

21.      Find out the radius of capillary in which Hg is fall down to 0.60 mm height. Surface tension of Hg = 0.485 N/m, density of Hg = 13600 Kg/m3, gravitational acceleration = 9.8 m/s2 and contact angle is 130°.


All the Best

In the exam attempt all questions.

Write in the proper sequence.

Use a diagram or chart to explain your theory.

Make the answer attractive.

Write Pointwise.

Don't attempt extra/or questions, they consume your time and not consider in the final total marks.


Trust in yourself and Never do copy from others.

Wish you all the Best.